I've noticed over a few months the grout along the bottom of the wall tiles connecting to the floor are sometimes wet looking. This is the master ensuite next to the toilet which is then next to the shower. The wet grout is only on the toilet side, not noticeable between the toilet and shower. Sometimes a white residue shows up on the floor tiles which looks like residue of a dried up spill, yet I've never seen any pooling.
There have been weeks where there is no wetness and there has been no change is usage of the room. On the other side of the wall is guest ensuite which has no issues visible, so this only appears to be an issue from the master ensuite side.
What's the right approach here to fix this? Is it the toilet leaking, or other plumbing, or perhaps even the shower leaking around the tiles and toilet to the other side? Do I just need to re-grout the tiles and re-silicone the shower/toilet? How do I remove a toilet if needed?
Here are some photos, which might be hard to decipher, so I'll do my best to add descriptions.
Rear of toilet, silicone meets tiles, appears wet and some brown growth/gunk build up. (photo is upside-down)

Rear of toilet, same gunk on other side against tiles, white residue on tiles, shower frame on right.

Another pic of the wet gunk on the toilet at rear where tiles join wall/floor

Tiles along wall (not shower side) and floor where the wet grout was first noticeable.

Rear/side of toilet adjacent to wall (opposite side from shower)

Holistic view of space
